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javaee_web_services_1_3.xsd has an entry in the catalog but is missing. This makes it impossible to create and validate a webservices.xml deployment descriptor. In the Enteprise Deployment Descriptors catalog there is an entry for http://java.sun.com/xml/ns/javaee/javaee_web_services_1_3.xsd that points to nbres:/org/netbeans/modules/j2ee/ddloaders/catalog/resources/javaee_web_services_1_3.xsd javaee_web_services_1_3.xsd should appear in enterprise\modules\org-netbeans-modules-j2ee-ddloaders.jar,org\netbeans\modules\j2ee\ddloaders\catalog\resources\ The file can be obtained from http://www.oracle.com/webfolder/technetwork/jsc/xml/ns/javaee/index.html#6
strange, it was missed for a few years. http://hg.netbeans.org/web-main/rev/d79876dfeda6